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102-51-2
  • 4-甲氧基邻苯二胺

  • names:

    4-Methoxybenzene-1,2-diamine

  • CAS号:

    102-51-2

    MDL Number: MFCD00047837
  • MF(分子式): C7H10N2O MW(分子量): 138
  • EINECS: Reaxys Number:
  • Pubchem ID: Brand:BIOFOUNT
4-甲氧基邻苯二胺
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中文别名 4-甲氧基邻苯二胺(102-51-2)
英文别名 4-Methoxy-1,2-benzenediamine:(102-51-2)
CAS号 102-51-2
SMILES COc1ccc(c(c1)N)N
Inchi InChI=1S/C7H10N2O/c1-10-5-2-3-6(8)7(9)4-5/h2-4H,8-9H2,1H3
InchiKey AGAHETWGCFCMDK-UHFFFAOYSA-N
分子式 Formula C7H10N2O
分子量 Molecular Weight 138
闪点 FP 161.7±16.0 °C
熔点 Melting point 46 - 50℃
沸点 Boiling point 302.4±22.0 °C at 760 mmHg
Polarizability极化度 16.4±0.5 10-24cm3
密度 Density 1.2±0.1 g/cm3
蒸汽压 Vapor Pressure 0.0±0.6 mmHg at 25°C
溶解度Solubility
性状
储藏条件 Storage conditions storage at -4℃ (1-2weeks), longer storage period at -20℃ (1-2years)
4-甲氧基邻苯二胺(102-51-2)实验注意事项:
1.实验前需戴好防护眼镜,穿戴防护服和口罩,佩戴手套,避免与皮肤接触。
2.实验过程中如遇到有毒或者刺激性物质及有害物质产生,必要时实验操作需要手套箱内完成以免对实验人员造成伤害。
3.取样品的移液枪头需及时更换,必要时为避免交叉污染尽可能选择滤芯吸头。
4.称量药品时选用称量纸,并无风处取药和称量以免扬撒,试剂的容器使用前务必确保干净,并消毒。
5.取药品时尽量采用多个药勺分别使用,使用后清洗干净后,烘干消毒存放。
6.实验后产生的废弃物需分类存储,并交于专业生物废气物处理公司处理,以免造成环境污染。
Experimental considerations:
1. Wear protective glasses, protective clothing and masks, gloves, and avoid contact with the skin during the experiment.
2. The waste generated after the experiment needs to be stored separately, and handed over to a professional biological waste gas treatment company to avoid environmental pollution.
产品说明 4-甲氧基邻苯二胺(102-51-2):仅做科学研究以及化学合成中间体使用,102-51-2其他参数见主页
Introduction4-Methoxy-1,2-benzenediamine:(102-51-2) used for scientific research and chemical synthesis intermediates
Application1
Application2
Application3
Pu GuoThese two authors contributed equally to this work., Xiaowei Xu, Xiaoyu Qiu, Yimin Zhou, Shengyong Yan, Changcheng Wang, Chunjiang Lu, Wen Ma, Xiaocheng Weng, Xianzheng Zhang and Xiang Zhou.Synthesis and spectroscopic properties of fluorescent 5-benzimidazolyl-2′-deoxyuridines 5-fdU probes obtained from o-phenylenediamine derivatives,Org. Biomol. Chem., 2013, 11, 1610.[DOI: 10.1039c3ob27519a]
Fluorometric determination of formaldehyde,Fresenius' Journal of Analytical Chemistry[DOI: 10.1007s002160050488]
Selective synthesis of benzene-1,3-diamines by amination of anilines containing orthopara-orienting substituents in the para position,Russian Journal of Organic Chemistry[DOI: 10.1134S1070428015030264]
Grimmett, M. R., Science of Synthesis, (2002) 12, 536..Reaction with Monocarboxylic Acids,Science of SynthesisGrimmett, M. R., Science of Synthesis, (2002) 12, 543..Via Palladium-Catalyzed Carbonylation of Iodobenzene,Science of SynthesisKleemann, A.; Engel, J.; Kutscher, B.; Reichert, D., Pharmaceutical Substances [Online], Thieme: Stuttgart, (2003)..
Omeprazole,Pharmaceutical SubstancesGobec, S.; Urleb, U., Science of Synthesis, (2004) 16, 849..From Benzene-1,2-diamines and 1,2-Diketones,Science of SynthesisTymoshenko, D. O., Science of Synthesis Knowledge Updates, (2012) 3, 348..
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