559-51-3|Kopsinine|methyl (3aS,3a1R,5R,5aR,10bS)-2,3,4,5,11,12-hexahydro-1H,3a1H,6H-3a,5a-ethanoindolizino[8,1-cd]carbazole-5-carboxylate|-范德生物科技公司

Kopsinine

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names：
methyl (3aS,3a1R,5R,5aR,10bS)-2,3,4,5,11,12-hexahydro-1H,3a1H,6H-3a,5a-ethanoindolizino[8,1-cd]carbazole-5-carboxylate
CAS号：
559-51-3
MDL Number：
MF(分子式)： C21H26N2O2 MW(分子量)： 338.45
EINECS: Reaxys Number:
Pubchem ID: Brand:BIOFOUNT

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中文别名	Kopsinine
英文别名	Kopsinine;
CAS号	559-51-3
Inchi	InChI=1S/C21H26N2O2/c1-25-17(24)15-13-19-7-4-11-23-12-10-20(18(19)23)14-5-2-3-6-16(14)22-21(15,20)9-8-19/h2-3,5-6,15,18,22H,4,7-13H2,1H3/t15-,18+,19-,20-,21+/m0/s1
InchiKey	IYLRRIUNGGQRTN-KDJJVYBXSA-N
分子式 Formula	C21H26N2O2
分子量 Molecular Weight	338.45
溶解度Solubility
性状	Solid powder
储藏条件 Storage conditions	Dry, dark and store at 0-4℃ for short term (days to weeks) or -20℃ for long term (Store correctly 2-3years).

产品说明	Kopsinine(CAS:559-51-3):仅限应用于工业或者科学研究过程中非医疗目的，不应用于人类或动物的临床诊断以及治过程疗，该产品非药用，非食用。
Introduction	Kopsinine is a plant alkaloid with anti-cholinergic activity.
Application1
Application2
Application3

警示图
危险性	Warning
危险性警示
安全声明
安全防护
备注

[1]Xie J, Wolfe AL, Boger DL. Total synthesis of kopsinine. Org Lett. 2013 Feb 15;15(4):868-70. doi: 10.1021/ol303573f. Epub 2013 Feb 7. PubMed PMID: 23391149; PubMed Central PMCID: PMC3578506.

[2]Lee K, Boger DL. Total synthesis of (-)-kopsinine and ent-(+)-kopsinine. Tetrahedron. 2015 Jun 3;71(22):3741-3746. PubMed PMID: 26074629; PubMed Central PMCID: PMC4461145.

[3] Harada S, Sakai T, Takasu K, Yamada K, Yamamoto Y, Tomioka K. Total synthesis of (-)-kopsinine by an asymmetric one-pot [n+2+3] cyclization. Chem Asian J. 2012 Oct;7(10):2196-8. doi: 10.1002/asia.201200575. Epub 2012 Aug 21. PubMed PMID: 22907720.

[4] Huang WY, Liu GT. [Mechanism of the protective action of kopsinine against hepatotoxicity of carbon tetrachloride]. Zhongguo Yao Li Xue Bao. 1989 Sep;10(5):461-4. Chinese. PubMed PMID: 2618736.

[5] Huang WY, Liu GT. [Protective action of kopsinine against experimental liver injuries in mice]. Zhongguo Yao Li Xue Bao. 1989 Jan;10(1):65-8. Chinese. PubMed PMID: 2816405.

6: Cheenpracha S, Raksat A, Ritthiwigrom T, Laphookhieo S. Monoterpene indole alkaloids from the twigs of Kopsia arborea. Nat Prod Commun. 2014 Oct;9(10):1441-3. PubMed PMID: 25522533.7: Huang WY, Liu GT. [Induction by kopsinine of hepatic mixed-function oxidase in mice]. Zhongguo Yao Li Xue Bao. 1990 May;11(3):264-8. Chinese. PubMed PMID: 2088003.8: Zhang J, Liu GT. [Protective action of kopsinine F against experimental liver injury in mice]. Yao Xue Xue Bao. 1989;24(3):165-9. Chinese. PubMed PMID: 2816370.9: Tan MJ, Yin C, Tang CP, Ke CQ, Lin G, Ye Y. Antitussive indole alkaloids from Kopsia hainanensis. Planta Med. 2011 Jun;77(9):939-44. doi: 10.1055/s-0030-1250631. Epub 2010 Dec 16. PubMed PMID: 21165819.10: Sears JE, Boger DL. Tandem Intramolecular Diels-Alder/1,3-Dipolar Cycloaddition Cascade of 1,3,4-Oxadiazoles: Initial Scope and Applications. Acc Chem Res. 2016 Feb 16;49(2):241-51. doi: 10.1021/acs.accounts.5b00510. Epub 2016 Jan 27. PubMed PMID: 26813287; PubMed Central PMCID: PMC4755904.1

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