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288-32-4
  • names:

    Imidazole

  • CAS号:

    288-32-4

    MDL Number: MFCD00005183
  • MF(分子式): C3H4N2 MW(分子量): 68.08
  • EINECS:206-019-2 Reaxys Number:103853
  • Pubchem ID:24896072 Brand:BIOFOUNT
咪唑
咪唑(Imidazole,288-32-4)也称为乙二醛或1,3-二唑,属于称为咪唑的有机化合物。 咪唑是含有咪唑环的化合物,该咪唑环是在位置1和3具有两个氮原子和三个碳原子的芳族五元环。 咪唑以固体,可溶(溶于水)和弱酸性化合物(基于其pKa)存在。 咪唑已经在大多数人体组织中发现,也主要在尿液中发现。 在细胞内,咪唑主要位于细胞质中。 咪唑可以转化为4-氨基咪唑和2-硝基咪唑。
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中文别名 咪唑(CAS:288-32-4);1,3-二氮唑; 1H-咪唑; 甘恶啉; 咁噁啉; 间二氮茂; 1-(2-甲基丙基)-4-氯-1H-咪唑并(4,5-c)喹啉; 1,3-二氨杂环戊二烯; 1,3-二氮杂茂; 1,3-二氮杂-2,4-环戊二烯; 甘啉; 引朵; IMZ; 咁恶啉
英文别名 Imidazole(CAS:288-32-4);imidazole; 1H-Imidazole; Glyoxaline; Imidazol; Iminazole; Miazole; 1,3-Diazole; Glyoxalin; Imutex
CAS号 288-32-4
SMILES c1cnc[nH]1
Inchi InChI=1S/C3H4N2/c1-2-5-3-4-1/h1-3H,(H,4,5)
InchiKey RAXXELZNTBOGNW-UHFFFAOYSA-N
分子式 Formula C3H4N2
分子量 Molecular Weight 68.08
闪点 FP 145℃
熔点 Melting point 90-91°C
沸点 Boiling point 257°C
Polarizability极化度 7.4±0.5 10-24cm3
密度 Density 1.1±0.1 g/cm3
蒸汽压 Vapor Pressure 0.0±0.5 mmHg at 25°C
溶解度Solubility
性状 Colorless crystals
储藏条件 Storage conditions 密封阴凉干燥保存。
咪唑(Imidazole,288-32-4)毒理性质:
测试 系统 动物 剂量 影响
Mutation Data DNA inhibition other cell types/human 1 mmol/L  
Reproductive Effects   intraperitoneal/mouse 150 mg/kg (1D male) Reproductive: Paternal effects: Impotence
Acute Toxicity Data   In Vitro/ada Inhibitor Concentration Low: 20 pph/240M In Vitro Toxicity Studies: Other assays
Acute Toxicity Data   In Vitro/Human, liver tumor Inhibitor Concentration (50 percent kill): 45 mmol/L/24H In Vitro Toxicity Studies: Cell protein synthesis
Acute Toxicity Data   In Vitro/jvx Inhibitor Concentration (50 percent kill): >50 µmol/L/24H In Vitro Toxicity Studies: Cell viability (mitochondrial reductase assays): MTT, XTT, MTS, WSTs assays etc.
Acute Toxicity Data   In Vitro/Rabbit, ocular Inhibitor Concentration Low: 5 pph/5M In Vitro Toxicity Studies: Cell viability (mitochondrial reductase assays): MTT, XTT, MTS, WSTs assays etc.
Acute Toxicity Data   intraperitoneal/mouse lethal dose (50 percent kill): 300 mg/kg  
Acute Toxicity Data   intravenous/mouse lethal dose (50 percent kill): 475 mg/kg Behavioral: Convulsions or effect on seizure threshold
Acute Toxicity Data   oral/guinea pig lethal dose (50 percent kill): 760 mg/kg  
Acute Toxicity Data   oral/mammal (species unspecified) lethal dose (50 percent kill): 1 gm/kg  
Acute Toxicity Data   oral/mouse lethal dose (50 percent kill): 880 mg/kg  
Acute Toxicity Data   oral/rat lethal dose (50 percent kill): 220 mg/kg  
Acute Toxicity Data   subcutaneous/cat lowest published lethal dose: 125 mg/kg Behavioral: Food intake (animal); Behavioral: Rigidity (includes catalepsy); Nutritional and Gross Metabolic: Body temperature decrease
Acute Toxicity Data   subcutaneous/Dog lethal dose (50 percent kill): 28 mg/kg  
Acute Toxicity Data   subcutaneous/mouse lethal dose (50 percent kill): 817 mg/kg  
Acute Toxicity Data   subcutaneous/rat lethal dose (50 percent kill): 626 mg/kg  

咪唑(CAS:288-32-4;英文名:Imidazole;)实验注意事项:
1.使用288-32-4实验前需戴好防护眼镜,穿戴防护服和口罩,佩戴手套,避免与皮肤接触。
2.使用288-32-4实验过程中如遇到有毒或者刺激性物质及有害物质产生,必要时实验操作需要手套箱内完成以免对实验人员造成伤害。
3.取样品288-32-4的移液枪头需及时更换,必要时为避免交叉污染尽可能选择滤芯吸头。
4.称量药品时选用称量纸,并无风处取药和称量以免扬撒,试剂的容器使用前务必确保干净,并消毒。
5.取药品288-32-4时尽量采用多个药勺分别使用,使用后清洗干净。
6.实验后产生的废弃物需分类存储,并交于专业生物废气物处理公司处理,以免造成环境污染。
大规格定制:定制产品请将信息发送至sales@bio-fount.com。
Experimental considerations:
1. Wear protective glasses, protective clothing and masks, gloves, and avoid contact with the skin during the experiment.
2. The waste generated after the experiment needs to be stored separately, and handed over to a professional biological waste gas treatment company to avoid environmental pollution.

Tag:咪唑蒸汽压,咪唑合成,咪唑标准,咪唑应用,咪唑合成,咪唑沸点,咪唑闪点,咪唑用途,咪唑溶解度,咪唑价格,咪唑作用,咪唑结构式,咪唑用处
产品说明 咪唑(288-32-4)也称为乙二醛或1,3-二唑,属于称为咪唑的有机化合物.咪唑溶解度,咪唑MSDS,咪唑结构式详见主页.
IntroductionImidazole(咪唑,288-32-4)also known as glyoxaline or 1, 3-diazole, belongs to the class of organic compounds known as imidazoles.
Application1Imidazoles are compounds containing an imidazole ring, which is an aromatic five-member ring with two nitrogen atoms at positions 1 and 3, and three carbon atoms.
Application2Imidazole exists as a solid, soluble (in water), and a very weakly acidic compound (based on its pKa).
Application3Imidazole has been found throughout most human tissues, and has also been primarily detected in urine.
1.1H-imidazole is an imidazole tautomer which has the migrating hydrogen at position 1. It is a mancude organic heteromonocyclic parent, a monocyclic heteroarene and an imidazole. It is a conjugate base of an imidazolium cation. It is a conjugate acid of an imidazolide. It is a tautomer of a 4H-imidazole.
2.Imidazole, also known as glyoxaline or 1, 3-diazole, belongs to the class of organic compounds known as imidazoles. Imidazoles are compounds containing an imidazole ring, which is an aromatic five-member ring with two nitrogen atoms at positions 1 and 3, and three carbon atoms. Imidazole exists as a solid, soluble (in water), and a very weakly acidic compound (based on its pKa). Imidazole has been found throughout most human tissues, and has also been primarily detected in urine. Within the cell, imidazole is primarily located in the cytoplasm. Imidazole can be converted into 4-aminoimidazole and 2-nitroimidazole.
警示图
危险性 warning
危险性警示 Not Available
安全声明 H302,H314,H360D
安全防护 P201,P280,P305+P351+P338,P310
备注 避免吸入,误食以及与皮肤接触
Electron-induced chemistry in imidazole clusters embedded in helium nanodroplets The European Physical Journal D 2018
Role of size and shape selectivity in interaction between gold nanoclusters and imidazole: a theoretical study Journal of Molecular Modeling 2014 25488624
Synthesis of novel three compound imidazole derivatives via Cu(II) catalysis and their larvicidal and antimicrobial activities Monatshefte für Chemie - Chemical Monthly 2016
Synthesis, Crystal Structure, DFT Modeling and Biological Activity of a Trinuclear Copper(II) Azide Polymer Containing Imidazole and Bridging Imidazolate Ligands, [Cu3(Imz-H)4(Imz)2(N3)4]n Journal of
Complex formation between imidazole and carboxylate ligands in aqueous solution Journal of Solution Chemistry 1993
1.Healing through Histidine: Bioinspired Pathways to Self-Healing Polymers via Imidazole?Metal Coordination/PMID 31105205; Biomimetics (Basel, Switzerland) 2019 Feb; 4(1): (Review Article)/Name matches: histidine imidazole
Abstract:
Biology offers a valuable inspiration toward the development of self-healing engineering composites and polymers. In particular, chemical level design principles extracted from proteinaceous biopolymers, especially the mussel byssus, provide inspiration for design of autonomous and intrinsic healing in synthetic polymers. The mussel byssus is an acellular tissue comprised of extremely tough protein-based fibers, produced by mussels to secure attachment on rocky surfaces. Threads exhibit self-healing response following an apparent plastic yield event, recovering initial material properties in a time-dependent fashion. Recent biochemical analysis of the structure-function relationships defining this response reveal a key role of sacrificial cross-links based on metal coordination bonds between Zn2+ ions and histidine amino acid residues. Inspired by this example, many research groups have developed self-healing polymeric materials based on histidine (imidazole)-metal chemistry. In this review, we provide a detailed overview of the current understanding of the self-healing mechanism in byssal threads, and an overview of the current state of the art in histidine- and imidazole-based synthetic polymers.
2.Ruthenium coordination preferences in imidazole-containing systems revealed by electrospray ionization mass spectrometry and molecular modeling: Possible cues for the surprising stability of the Ru (III)/tris (hydroxymethyl)-aminomethane/imidazole complexes/PMID 31508870; Journal of mass spectrometry : JMS 2020 Feb; 55(2):e4435/Name matches: histidine imidazole
Abstract:
Ruthenium is a platinoid that exhibits a range of unique chemical properties in solution, which are exploited in a variety of applications, including luminescent probes, anticancer therapies, and artificial photosynthesis. This paper focuses on a recently demonstrated ability of this metal in its +3 oxidation state to form highly stable complexes with tris (hydroxymethyl)aminomethane (H2 NC(CH2 OH)3 , Tris-base or T) and imidazole (Im) ligands, where a single RuIII cation is coordinated by two molecules of each T and Im. High-resolution electrospray ionization mass spectrometry (ESI MS) is used to characterize RuIII complexes formed by placing a RuII complex [(NH3 )5 RuII Cl]Cl in a Tris buffer under aerobic conditions. The most abundant ionic species in ESI MS represent mononuclear complexes containing an oxidized form of the metal, ie, [Xn RuIII T2 - 2H]+ , where X could be an additional T (n = 1) or NH3 (n = 0-2). Di- and tri-metal complexes also give rise to a series of abundant ions, with the highest mass ion representing a metal complex with an empirical formula Ru3 C24 O21 N6 H66 (interpreted as cyclo(T2 RuO)3 , a cyclic oxo-bridged structure, where the coordination sphere of each metal is completed by two T ligands). The empirical formulae of the binuclear species are consistent with the structures representing acyclic fragments of cyclo(T2 RuO)3 with addition of various combinations of ammonia and dioxygen as ligands. Addition of histidine in large molar excess to this solution results in complete disassembly of poly-nuclear complexes and gives rise to a variety of ionic species in the ESI mass spectrum with a general formula [RuIII Hisk Tm (NH3 )n - 2H]+ , where k = 0 to 2, m = 0 to 3, and n = 0 to 4. Ammonia adducts are present for all observed combinations of k and m, except k = m = 2, suggesting that [His2 RuIII T2 - 2H]+ represents a complex with a fully completed coordination sphere. The observed cornucopia of RuIII complexes formed in the presence of histidine is in stark contrast to the previously reported selective reactivity of imidazole, which interacts with the metal by preserving the RuT2 core and giving rise to a single abundant ruthenium complex (represented by [Im2 RuIII T2 - 2H]+ in ESI mass spectra). Surprisingly, the behavior of a hexa-histidine peptide (HHHHHH) is similar to that of a single imidazole, rather than a single histidine amino acid: The RuT2 core is preserved, with the following ionic species observed in ESI mass spectra: [HHHHHH·(RuIII T2 )m - (3m-1)H]+ (m = 1-3). The remarkable selectivity of the imidazole interaction with the RuIII T2 core is rationalized using energetic considerations at the quantum mechanical level of theory.
3.Pyrene-imidazole conjugate as a fluorescent sensor for the sequential detection of iron(III) and histidine in aqueous solution/PMID 31718975; Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 2020 Mar; 228:117725
Name matches: histidine imidazole
Abstract:
We developed PIM, a pyrene-based fluorescence sensor bearing an imidazole moiety and a carbonyl group as the binding sites for Fe3+ ions. The pyrene-based control compounds 1 and 2 were synthesized to demonstrate the structure-activity relationships. Compound 1, which contained a thiazoline moiety and a carbonyl group, displayed high selectivity for Cu2+ ions. This property indicated that heterocycles play an important role in the metal ion selectivity modulation. Compound 2, which lacked a carbonyl group, did not display metal ion selectivity. This characteristic demonstrated that introducing an additional recognition unit (cooperative recognition strategy) should be an effective way to improve metal ion selectivity. Furthermore, the PIM-Fe3+ ensemble can serve as a fluorescent sensor for histidine (His) detection via the removal of Fe3+ from the ensemble by His and the release of PIM. The sequential detection of Fe3+ and His exhibited on-off-on phenomenon, and the Fe3+ and His detection limits were 0.11 and 3.06 μM, respectively. These results will help in the further enhancement or modulation of metal ion selectivity in the development of fluorescent sensor systems. Moreover, the organic-metal ensemble provides an effective platform for detecting amino acids through the displacement strategy.
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Ren 化学品安全技术说明书

版本1.0

按照GB/T16483GB/T17519编制

修订日期10.07.2019

 

打印日期19.02.2020

版权所有:范德(北京)生物科技有限责任公司

最初编制日期25.05.2017

公司网站:WWW.BIO-FOUNT.COM

SDS编号BIOFOUNT-JP0001

版权所有:BIOFOUNT BEIJING BIO TECH CO.,LTD

产品编号JP0001

咪唑

说明书目录

1部分

化学品及企业标识

2部分

危险性概述

3部分

成分/组成信息

4部分

急救措施

5部分

消防措施

6部分

泄露应急处理

7部分

操作处置与储存

8部分

接触控制/个体防护

9部分

理化性质

10部分

稳定性和反应性

11部分

毒理学信息

12部分

生态学危害信息

13部分

废弃处置

14部分

运输信息

15部分

法律法规信息

16部分

其他补充信息

1部分:化学品及企业标识

1.1 产品标识

产品名称:

咪唑

ENGLISH NAME

Imidazole

产品编号:

JP0001

品牌:

BIOFOUNT

化学文摘登记号(CAS NO.):

288-32-4

1.2 安全技术说明书提供者的详情

制造商或供应商名称

BIOFOUNT BEIJING BIO-TECH CO.,LTD

制造地址:

59 KANGTAI AVENUE BINHAI NEW DISTRICT TIANJIN

300450 TIANJIN CHINA

范德(天津)生物科技有限责任

天津市滨海新区康泰大道59号九州通绿谷健康产业园

邮政编码:300450

电话号码

 

1.3 应急咨询电话

紧急联系电话

 

1.4 物质或混合物的推荐用途和限制用途

已确认的各用途

仅用于科学研发不作为药品、家庭或其它用途。

2部分:危险性概述

2.1 GHS危险性类别

暂无数据

2.2 GHS 标签要素,包括防范说明

象形图

暂无数据

信号词

Danger

危险申明

H302,H314,H360D

警告申明

避免吸入,误食以及与皮肤接触

预防措施

P201,P280,P305+P351+P338,P310

事故响应

1.化学品使用过程中,当出现事故或者有紧急情况发生时,当事人应第一时间向应急小组负责人汇报后,由应急小组采取措施防止事态扩大。2.应急小组对受害人采取救护措施。

储存

密封阴凉干燥保存。

废弃处置

暂无数据

2.3 物理和化学危险

暂无数据

2.4 健康危害

暂无数据

2.5 环境危害

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2.6 其它危害物

暂无数据

3部分:成分/组成信息

物质/混合物

暂无数据

3.1 物 质

分子式

C3H4N2

分子量

68.08

化学文摘登记号(CAS NO.)

110-91-8

EC-编号

206-019-2

根据相应法规,无需披露具体组份。

4部分:急救措施

4.1 必要的急救措施描述

吸入

立即将患者移至空气新鲜处,发现呼吸困难时,必须立即采取吸氧处理,停止呼吸时采取人工呼吸。同时联系及时就医。

皮肤接触

立即脱去或者剪去污染的衣物,迅速用大量的流动清水冲10-20分钟甚至更长时间后,赴医院就医。

眼睛接触

立即用大量的流动清水冲10-20分钟后赴医院就医处理。

食入

误食化学物品后,应立即采取措施进行催吐。1.若误食化学品呈酸性,则可服用大量牛奶和水,促使食如折呕吐。2.若误食化学品呈碱性,则可服用大量牛奶、清水和醋,促使其呕吐,紧急处理后,应及时送至医院进行治疗(仅供参考)。食如者昏迷状态下禁止催吐,以免造成窒息。

4.2 最重要的症状和健康影响

最重要的已知症状及作用已在标签(参见章节2.2)和/或章节11中介绍

4.3 及时的医疗处理和所需的特殊处理的说明和指示

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4.4 对医生的特别提示

暂无数据

5部分:消防措施

5.1 灭火介质

灭火方法及灭火剂

采用泡沫灭火器、二氧化碳灭火器,避免造成二次污染发生。

5.2  源于此物质或混合物的特别的危害

暂无数据

5.3 灭火注意事项及保护措施

小规模着火需戴好口罩,防止有毒气体吸入。火灾发生时及时启动应急相应系统撤离至上风口处,并联系当地消防部门灭火。

6部分:泄露应急处理

6.1 人员防护措施、防护装备和应急处置程序

1.泄露后首先启动应急相应系统2.泄露处理前,需穿戴好安全安全防护鞋、穿戴好安全防护手套(强酸性物质需穿戴防酸碱手套)、根据吸入危险性穿戴相应防护面罩。

有关个人防护请看第8部分

6.2 环境保护措施

参照《范德生物化学废弃物处理方法》处理,防止对环境造成危害,处理后交由有资质的废弃物处理结构进行处理,以免造成环境污染。

6.3 泄漏化学品的收容、清除方法及所使用的处置材料

参照《范德生物化学品废弃物处理方法》对泄露的化学品进行处理,处理前需用化学品吸附岩棉对泄露区域进行围挡,形成“围堰”防止泄露扩大。

6.4 参考其他部分

丢弃处理请参阅第13节。

7部分:操作处置与储存

7.1 安全操作的注意事项

使用过程请穿戴好口罩,手套等防护用品,避免与皮肤接触、吸入、误食危险。

有关预防措施,请参见章节2.2

7.2  安全储存的条件,包括任何不兼容性

暂时无法提供详细数据,尽可能避免与其他化合物混合存储,避光、通风处存储。

8部分:接触控制/个体防护

8.1 控制参数

危害组成及职业接触限值

暂无数据

8.2 暴露控制

适当的技术控制

暂无数据

个体防护装备

眼面防护

一般情况下穿戴安全防护眼镜即可,如有飞溅液体、粉末产生时,请佩戴防溅面罩进行防护。穿戴的防护用品需取得如:GBNIOSH (美国) EN 166(欧盟) 等相关认证

皮肤保护

手套脱去注意事项:手套在使用前必须进行检查请使用正确的方法脱除手套(不接触手套外部表面)避免身体任何皮肤部位接触此产品根据相关法律法规和实验室管理规范制度,手套使用请将被污染的手套谨慎处理,工作后清洗并吹干双手

所选择的保护手套必须符合法规《劳动防护用品配备标准》、(EU)2016/425以及此类法规衍生出来的EN 374标准规范

完全接触保护要求:

手套材料丁腈橡胶

手套最小的层厚度0.11 MM

手套溶剂渗透时间480 分钟

飞溅保护要求:

材料丁腈橡胶

最小的层厚度 0.11 MM

溶剂渗透时间480 分钟

如果以溶剂形式应用或与其它物质混合应用或在不同于《劳动防护用品配备标准》,EN 374规定的条件下应用请与EC批准的手套的供应商联系。该条只是作为推荐建议,如遇特殊情况,务必请熟悉该产品属性的专家,选取相关防护用品。此条建议不应该被认定为适应所有特殊条件防护,请根据所处工作条件请求专业工程师指导采取相应防护措施。

身体保护

选择身体部分的防护措施,需要根据危险物质的类型浓度量以及特定的工作环境身体部分防护设备、防护服的类型必须根据使用者工作场所中的危险物质的浓度数量进行选择。

呼吸系统防护

一般情况下穿戴普通的医用口罩保护呼吸系统即可有酸雾产生式活性炭类口罩起不到防护作用,如需粉尘造成损害进行防护时,请采用N95型(US)或P1型(EN 143)类口罩或者防尘面具。特殊情况下使用自吸式呼吸器时,使用的呼吸器必须对呼吸器密闭性、空气供应系统、供气压进行测试,当然呼吸器需通过强制认证标准如GBNIOSHUSCENEU)。

环境暴露的控制

不要让产品进入下水道。

9部分:理化特性

9.1 基本的理化特性的信息

外观与性状

形状暂无数据

 

颜色暂无数据

气味

暂无数据

气味阈值

暂无数据

PH值

暂无数据

熔点/凝固点

90-91°C

初沸点和沸程

257°C

闪点

145℃

蒸发速率

暂无数据

易燃性(固体,气体)

暂无数据

高的/低的燃烧性或爆炸性限度

暂无数据

蒸气压

0.0±0.5 mmHg at 25°C

蒸气焓

47.5±3.0 kJ/mol

密度/相对密度

1.0975

溶解度

Miscible with water, ethanol, ether, acetone, chloroform, pyridine and methanol. Slightly miscible with benzene and petroleum ether.

正辛醇/水分配系数

Log Kow (KOWWIN v1.67 estimate) = 0.06 Log Kow (Exper. database match) = -0.08 Exper. Ref: Hansch,C et al. (1995)/ Boiling Pt, Melting Pt, Vapor Pressure Estimations (MPBPWIN v1.42): Boiling Pt (deg C): 240.06 (Adapted Stein & Brown method) Melting Pt (deg C): 18.52 (Mean or Weighted MP) VP(mm Hg,25 deg C): 0.00434 (Modified Grain method) MP (exp database): 90.5 deg C BP (exp database): 257 deg C Subcooled liquid VP: 0.0186 mm Hg (25 deg C, Mod-Grain method)

正辛醇空气分配系数

Log Kow used: -0.08 (exp database) Log Kaw used: -3.813 (HenryWin est) Log Koa (KOAWIN v1.10 estimate): 3.733 Log Koa (experimental database): None

自燃温度

暂无数据

分解温度

暂无数据

黏度

暂无数据

爆炸特性

暂无数据

氧化性

暂无数据

根据碎片估算水溶胶

Wat Sol (v1.01 est) = 1.3416e+005 mg/L

亨利定律常数(25摄氏度)

Bond Method : 3.76E-006 atm-m3/mole Group Method: Incomplete Henrys LC [VP/WSol estimate using EPI values]: 2.444E-009 atm-m3

9.2 其他安全信息

暂无数据

10部分:稳定性和反应性

10.1 稳定性

暂无数据

10.2 危险反应

暂无数据

10.3 应避免的条件

暂无数据

10.4 禁配物

强氧化剂

10.5 危险的分解产物

暂无数据

11部分:毒理学信息

11.1 毒理学影响信息

毒性

暂无数据

皮肤腐蚀/刺激

暂无数据

严重眼睛损伤/眼刺激

暂无数据

呼吸或皮肤过敏

暂无数据

生殖细胞致突变性

暂无数据

致癌性

暂无数据

生殖毒性

暂无数据

特异性靶器官系统毒性(一次接触)

暂无数据

特异性靶器官系统毒性(反复接触)

暂无数据

吸入危害

暂无数据

附加说明

暂无数据

12部分:生态学危害信息

12.1 生态毒性

暂无数据

12.2 持久性和降解性

暂无数据

12.3 快速生物降解的可能性

Biowin1 (Linear Model) : 0.7151 Biowin2 (Non-Linear Model) : 0.8851

12.4 专家调查生物降解结果

Biowin3 (Ultimate Survey Model): 3.0487 (weeks ) Biowin4 (Primary Survey Model) : 3.7495 (days-weeks )

12.5 MITI生物降解的可能性

Biowin5 (MITI Linear Model) : 0.5343 Biowin6 (MITI Non-Linear Model): 0.7152

12.6 厌氧生物降解的可能性

Biowin7 (Anaerobic Linear Model): 0.5498

12.7 现成的生物降解性预测

YES

12.8 碳氢化合物生物降解

Structure incompatible with current estimation method!

12.9 对气溶胶的吸附

Vapor pressure (liquid/subcooled): 2.48 Pa (0.0186 mm Hg) Log Koa (Koawin est ): 3.733 Kp (particle/gas partition coef. (m3/ug)): Mackay model : 1.21E-006 Octanol/air (Koa) model: 1.33E-009

12.10 羟基自由基反应

OVERALL OH Rate Constant = 36.0000 E-12 cm3/molecule-sec Half-Life = 0.297 Days (12-hr day; 1.5E6 OH/cm3) Half-Life = 3.565 Hrs

12.11 臭氧反应

No Ozone Reaction Estimation

12.12 空气中颗粒物吸附的分数(PHI

7.02E-005 (Junge,Mackay) Note: the sorbed fraction may be resistant to atmospheric oxidation

12.13 土壤吸附系数

暂无数据

12.14 /酸催化水解(25℃

Koc : 9.724 Log Koc: 0.988 / Aqueous Base/Acid-Catalyzed Hydrolysis (25 deg C) [HYDROWIN v1.67]: Rate constants can NOT be estimated for this structure!/

12.15 利用对数KOW估算生物累积量

Log BCF from regression-based method = 0.500 (BCF = 3.162) log Kow used: -0.08 (expkow database)

12.16 废水处理中的去除

Total removal: 2.06 percent Total biodegradation: 0.09 percent Total sludge adsorption: 1.75 percent Total to Air: 0.21 percent (using 10000 hr Bio P,A,S)

12.17 三级逸度模型

Mass Amount Half-Life Emissions (percent) (hr) (kg/hr) Air 1.04 7.15 1000 Water 48 360 1000 Soil 50.9 720 1000 Sediment 0.0884 3.24e+003 0 Persistence Time: 333 hr

12.18 土壤中的迁移性

暂无数据

12.19 PBTVPVB的结果评价

暂无数据

12.20 其他环境有害作用

暂无数据

13部分:废弃处置

13.1 废物处理

方法产品

None

污染包装物

None

14部分:运输信息

14.1 联合国编号 / UN NUMBER

欧洲陆运危规 / ER/RID

None

国际海运危规 / IMDG

None

国际空运危规 / IATA-DGR

None

14.2 联合国运输名称 / UN PROPER SHIPPING NAME

欧洲陆运危规 

None

国际海运危规

None

国际空运危规 

None

14.3 运输危险类别 / TRANSPORT HAZARD CLASS(ES)

欧洲陆运危规 / ER/RID

None

国际海运危规 / IMDG

None

国际空运危规 / IATA-DGR

None

14.4 包裹组 / PACKAGING GROUP

欧洲陆运危规 / ER/RID

None

国际海运危规 / IM0DG

None

国际空运危规 / IATA-DGR

None

14.5 环境危害 / ENVIRONMENTAL HAZARDS

None

14.6 特殊防范措施 / SPECIAL PRECAUTIONS FOR USER

None

14.7 禁配物 / INCOMPATIBLE MATERIALS

None

15部分:法律法规信息

15.1 专门对此物质或混合物的安全,健康和环境的规章/法规

适用法规

《中华人民共和国安全生产法》、《职业病防治法》、《化学化工实验室安全管理规范》

其它的规定

《生产安全事故报告和调查处理条例》、《职业病防治法》、《职业安全和卫生法》美国1970

16部分:其他补充信息

其他信息

版权所有:BIOFOUNT BEIJING BIO TECH CO.,LTD 公司。许可无限制纸张拷贝,仅限于内部使用。

上述信息视为正确,但不包含所有的信息,仅作为指引使用。本文件中的信息是基于我们目前所知,就正确的安全提示来说适用于本品。该信息不代表对此产品性质的保证。BIOFOUNT公司及其附属公司对任何操作或者接触上述产品而引起的损害不负有任何责任。更多使用条款,参见发票或包装条的反面。

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