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118864-75-8
  • (S)-1-苯基-1,2,3,4-四氢异喹啉

  • names:

    (1S)-1-Phenyl-1,2,3,4-tetrahydroisoquinoline

  • CAS号:

    118864-75-8

    MDL Number: MFCD08692036
  • MF(分子式): C15H15N MW(分子量): 209.29
  • EINECS:253662554 Reaxys Number:
  • Pubchem ID:4182092 Brand:BIOFOUNT
(S)-1-苯基-1,2,3,4-四氢异喹啉
货品编码 规格 纯度 价格 (¥) 现价(¥) 特价(¥) 库存描述 数量 总计 (¥)
HXH506470-5g 5g >98.0%(GC)(T) ¥ 1428.00 ¥ 1428.00 1-2days
- +
¥ 0.00
HXH506470-1g 1g >98.0%(GC)(T) ¥ 396.00 ¥ 396.00 1-2days
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¥ 0.00
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中文别名 (S)-1-苯基-1,2,3,4-四氢异喹啉(118864-75-8);(S)-1-苯基-1,2,3,4-四氢异喹啉
英文别名 (1S)-1-Phenyl-1,2,3,4-tetrahydroisoquinoline(cas:118864-75-8);(1S)-1-Phenyl-1,2,3,4-tetrahydroisoquinoline
CAS号 118864-75-8
SMILES c1ccc(cc1)[C@H]2c3ccccc3CCN2CopyCopied
Inchi InChI=1S/C15H15N/c1-2-7-13(8-3-1)15-14-9-5-4-6-12(14)10-11-16-15/h1-9,15-16H,10-11H2/t15-/m0/s1CopyCopied
InchiKey PRTRSEDVLBBFJZ-HNNXBMFYSA-NCopyCopied
分子式 Formula C15H15N
分子量 Molecular Weight 209.29
闪点 FP 166.9±14.7 °C
熔点 Melting point 87.0 to 91.0 deg-C
沸点 Boiling point 338.4±11.0 °C at 760 mmHg
Polarizability极化度
密度 Density 1.1±0.1 g/cm3
蒸汽压 Vapor Pressure 0.0±0.7 mmHg at 25°C
溶解度Solubility
性状 白色粉末
储藏条件 Storage conditions 4℃条件下存储,-4℃存储更佳
(S)-1-苯基-1,2,3,4-四氢异喹啉(118864-75-8)实验注意事项:
1.实验前需戴好防护眼镜,穿戴防护服和口罩,佩戴手套,避免与皮肤接触。
2.实验过程中如遇到有毒或者刺激性物质及有害物质产生,必要时实验操作需要手套箱内完成以免对实验人员造成伤害。
3.取样品的移液枪头需及时更换,必要时为避免交叉污染尽可能选择滤芯吸头。
4.称量药品时选用称量纸,并无风处取药和称量以免扬撒,试剂的容器使用前务必确保干净,并消毒。
5.取药品时尽量采用多个药勺分别使用,使用后清洗干净后,烘干消毒存放。
6.实验后产生的废弃物需分类存储,并交于专业生物废气物处理公司处理,以免造成环境污染。
Experimental considerations:
1. Wear protective glasses, protective clothing and masks, gloves, and avoid contact with the skin during the experiment.
2. The waste generated after the experiment needs to be stored separately, and handed over to a professional biological waste gas treatment company to avoid environmental pollution.
产品说明 (S-1-苯基-1,2,3,4-四氢异喹啉(118864-75-8;(1S)-1-Phenyl-1,2,3,4-tetrahydroisoquinoline):应用于生物科学研究,也可以作为有机合成中间体使用。
Introduction(1S)-1-Phenyl-1,2,3,4-tetrahydroisoquinoline(118864-75-8(S)-1-苯基-1,2,3,4-四氢异喹啉)can be use in research or as an intermediate in organic synthesis.
Application1
Application2
Application3
Efficient and single pot process for the preparation of enantiomerically pure solifenacin succinate, an antimuscarinic agent,Monatshefte f??r Chemie - Chemical Monthly
Enantioseparation of 1-Phenyl-1,2,3,4-tetrahydroisoquinoline on Polysaccharide-Based Chiral Stationary Phases,Chromatographia
Kleemann, A.; Engel, J.; Kutscher, B.; Reichert, D., Pharmaceutical Substances [Online]
, Thieme: Stuttgart, (2006)..Solifenacin,Pharmaceutical SubstancesBabu, R. Anji; Reddy, N. Siva Senkar; Reddy, B. Jagan Mohan; Reddy, B. V. Subba, Synthesis 2014, 46, 2794-2798.Stereoselective Total Syntheses of Solifenacin and N-Acetyl-1-(4-chloro?phenyl)-6,7-dimethoxytetrahydroisoquinoline,Synthesis
Pollegioni, L.; Molla, G..Oxidation of Large Amines by Monoamine Oxidase from Aspergillus niger,Science of Synthesis: Biocatalysis in Organic Synthesis, (2015) 3, 251.Lautens, Mark; B?rki, C?dric.Redox Deracemization of Tetrahydroiso-quinolines,Lautens, Mark; B?rki, C?dric, Synfacts 2015, 11, 1188
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Ren 化学品安全技术说明书

版本1.0

按照GB/T16483GB/T17519编制

修订日期10.07.2019

 

打印日期19.02.2020

版权所有:范德(北京)生物科技有限责任公司

最初编制日期25.05.2017

公司网站:WWW.BIO-FOUNT.COM

SDS编号BIOFOUNT-HXH506470

版权所有:BIOFOUNT BEIJING BIO TECH CO.,LTD

产品编号BIOFOUNT-HXH506470

(S)-1-苯基-1,2,3,4-四氢异喹啉

说明书目录

1部分

化学品及企业标识

2部分

危险性概述

3部分

成分/组成信息

4部分

急救措施

5部分

消防措施

6部分

泄露应急处理

7部分

操作处置与储存

8部分

接触控制/个体防护

9部分

理化性质

10部分

稳定性和反应性

11部分

毒理学信息

12部分

生态学危害信息

13部分

废弃处置

14部分

运输信息

15部分

法律法规信息

16部分

其他补充信息

1部分:化学品及企业标识

1.1 产品标识

产品名称:

(S)-1-苯基-1,2,3,4-四氢异喹啉

ENGLISH NAME

(1S)-1-Phenyl-1,2,3,4-tetrahydroisoquinoline

产品编号:

HXH506470

品牌:

BIOFOUNT

化学文摘登记号(CAS NO.):

118864-75-8

1.2 安全技术说明书提供者的详情

制造商或供应商名称

BIOFOUNT BEIJING BIO-TECH CO.,LTD

制造地址:

59 KANGTAI AVENUE BINHAI NEW DISTRICT TIANJIN

300450 TIANJIN CHINA

范德(天津)生物科技有限责任

天津市滨海新区康泰大道59号九州通绿谷健康产业园

邮政编码:300450

电话号码

 

1.3 应急咨询电话

紧急联系电话

 

1.4 物质或混合物的推荐用途和限制用途

已确认的各用途

仅用于科学研发不作为药品、家庭或其它用途。

2部分:危险性概述

2.1 GHS危险性类别

暂无数据

2.2 GHS 标签要素,包括防范说明

象形图

暂无数据

信号词

暂无数据

危险申明

暂无数据

警告申明

暂无数据

预防措施

暂无数据

事故响应

1.化学品使用过程中,当出现事故或者有紧急情况发生时,当事人应第一时间向应急小组负责人汇报后,由应急小组采取措施防止事态扩大。2.应急小组对受害人采取救护措施。

储存

暂无数据

废弃处置

暂无数据

2.3 物理和化学危险

暂无数据

2.4 健康危害

暂无数据

2.5 环境危害

暂无数据

2.6 其它危害物

暂无数据

3部分:成分/组成信息

物质/混合物

物质

3.1 物 质

分子式

C15H15N

分子量

209.29

化学文摘登记号(CAS NO.)

118864-75-8

EC-编号

暂无数据

根据相应法规,无需披露具体组份。

4部分:急救措施

4.1 必要的急救措施描述

吸入

立即将患者移至空气新鲜处,发现呼吸困难时,必须立即采取吸氧处理,停止呼吸时采取人工呼吸。同时联系及时就医。

皮肤接触

立即脱去或者剪去污染的衣物,迅速用大量的流动清水冲10-20分钟甚至更长时间后,赴医院就医。

眼睛接触

立即用大量的流动清水冲10-20分钟后赴医院就医处理。

食入

误食化学物品后,应立即采取措施进行催吐。1.若误食化学品呈酸性,则可服用大量牛奶和水,促使食如折呕吐。2.若误食化学品呈碱性,则可服用大量牛奶、清水和醋,促使其呕吐,紧急处理后,应及时送至医院进行治疗(仅供参考)。食如者昏迷状态下禁止催吐,以免造成窒息。

4.2 最重要的症状和健康影响

最重要的已知症状及作用已在标签(参见章节2.2)和/或章节11中介绍

4.3 及时的医疗处理和所需的特殊处理的说明和指示

暂无数据

4.4 对医生的特别提示

暂无数据

5部分:消防措施

5.1 灭火介质

灭火方法及灭火剂

采用泡沫灭火器、二氧化碳灭火器,避免造成二次污染发生。

5.2  源于此物质或混合物的特别的危害

暂无数据

5.3 灭火注意事项及保护措施

小规模着火需戴好口罩,防止有毒气体吸入。火灾发生时及时启动应急相应系统撤离至上风口处,并联系当地消防部门灭火。

6部分:泄露应急处理

6.1 人员防护措施、防护装备和应急处置程序

1.泄露后首先启动应急相应系统2.泄露处理前,需穿戴好安全安全防护鞋、穿戴好安全防护手套(强酸性物质需穿戴防酸碱手套)、根据吸入危险性穿戴相应防护面罩。

有关个人防护请看第8部分

6.2 环境保护措施

参照《范德生物化学废弃物处理方法》处理,防止对环境造成危害,处理后交由有资质的废弃物处理结构进行处理,以免造成环境污染。

6.3 泄漏化学品的收容、清除方法及所使用的处置材料

参照《范德生物化学品废弃物处理方法》对泄露的化学品进行处理,处理前需用化学品吸附岩棉对泄露区域进行围挡,形成“围堰”防止泄露扩大。

6.4 参考其他部分

丢弃处理请参阅第13节。

7部分:操作处置与储存

7.1 安全操作的注意事项

使用过程请穿戴好口罩,手套等防护用品,避免与皮肤接触、吸入、误食危险。

有关预防措施,请参见章节2.2

7.2  安全储存的条件,包括任何不兼容性

暂时无法提供详细数据,尽可能避免与其他化合物混合存储,避光、通风处存储。

8部分:接触控制/个体防护

8.1 控制参数

危害组成及职业接触限值

暂无数据

8.2 暴露控制

适当的技术控制

暂无数据

个体防护装备

眼面防护

一般情况下穿戴安全防护眼镜即可,如有飞溅液体、粉末产生时,请佩戴防溅面罩进行防护。穿戴的防护用品需取得如:GBNIOSH (美国) EN 166(欧盟) 等相关认证

皮肤保护

手套脱去注意事项:手套在使用前必须进行检查请使用正确的方法脱除手套(不接触手套外部表面)避免身体任何皮肤部位接触此产品根据相关法律法规和实验室管理规范制度,手套使用请将被污染的手套谨慎处理,工作后清洗并吹干双手

所选择的保护手套必须符合法规《劳动防护用品配备标准》、(EU)2016/425以及此类法规衍生出来的EN 374标准规范

完全接触保护要求:

手套材料丁腈橡胶

手套最小的层厚度0.11 MM

手套溶剂渗透时间480 分钟

飞溅保护要求:

材料丁腈橡胶

最小的层厚度 0.11 MM

溶剂渗透时间480 分钟

如果以溶剂形式应用或与其它物质混合应用或在不同于《劳动防护用品配备标准》,EN 374规定的条件下应用请与EC批准的手套的供应商联系。该条只是作为推荐建议,如遇特殊情况,务必请熟悉该产品属性的专家,选取相关防护用品。此条建议不应该被认定为适应所有特殊条件防护,请根据所处工作条件请求专业工程师指导采取相应防护措施。

身体保护

选择身体部分的防护措施,需要根据危险物质的类型浓度量以及特定的工作环境身体部分防护设备、防护服的类型必须根据使用者工作场所中的危险物质的浓度数量进行选择。

呼吸系统防护

一般情况下穿戴普通的医用口罩保护呼吸系统即可有酸雾产生式活性炭类口罩起不到防护作用,如需粉尘造成损害进行防护时,请采用N95型(US)或P1型(EN 143)类口罩或者防尘面具。特殊情况下使用自吸式呼吸器时,使用的呼吸器必须对呼吸器密闭性、空气供应系统、供气压进行测试,当然呼吸器需通过强制认证标准如GBNIOSHUSCENEU)。

环境暴露的控制

不要让产品进入下水道。

9部分:理化特性

9.1 基本的理化特性的信息

外观与性状

形状暂无数据

 

颜色暂无数据

气味

暂无数据

气味阈值

暂无数据

PH值

暂无数据

熔点/凝固点

87.0 to 91.0 deg-C

初沸点和沸程

338.4±11.0 °C at 760 mmHg

闪点

166.9±14.7 °C

蒸发速率

暂无数据

易燃性(固体,气体)

暂无数据

高的/低的燃烧性或爆炸性限度

暂无数据

蒸气压

0.0±0.7 mmHg at 25°C

蒸气焓

暂无数据

密度/相对密度

1.1±0.1 g/cm3

溶解度

暂无数据

正辛醇/水分配系数

Log POW:2.70

正辛醇空气分配系数

Log Kow used: 3.38 (KowWin est) Log Kaw used: -5.667 (HenryWin est) Log Koa (KOAWIN v1.10 estimate): 9.047 Log Koa (experimental database): None/

自燃温度

暂无数据

分解温度

暂无数据

黏度

暂无数据

爆炸特性

暂无数据

氧化性

暂无数据

根据碎片估算水溶胶

WatSol(v1.01est)=74.619mg/L

亨利定律常数(25摄氏度)

Bond Method : 5.27E-008 atm-m3/mole Group Method: Incomplete Henrys LC [VP/WSol estimate using EPI values]: 2.122E-008 atm-m3/mole/

9.2 其他安全信息

暂无数据

10部分:稳定性和反应性

10.1 稳定性

暂无数据

10.2 危险反应

暂无数据

10.3 应避免的条件

暂无数据

10.4 禁配物

强氧化剂

10.5 危险的分解产物

暂无数据

11部分:毒理学信息

11.1 毒理学影响信息

毒性

暂无数据

皮肤腐蚀/刺激

暂无数据

严重眼睛损伤/眼刺激

暂无数据

呼吸或皮肤过敏

暂无数据

生殖细胞致突变性

暂无数据

致癌性

暂无数据

生殖毒性

暂无数据

特异性靶器官系统毒性(一次接触)

暂无数据

特异性靶器官系统毒性(反复接触)

暂无数据

吸入危害

暂无数据

附加说明

暂无数据

12部分:生态学危害信息

12.1 生态毒性

暂无数据

12.2 持久性和降解性

暂无数据

12.3 快速生物降解的可能性

Biowin1 (Linear Model) : 0.9845 Biowin2 (Non-Linear Model) : 0.9713

12.4 专家调查生物降解结果

Biowin3 (Ultimate Survey Model): 2.7083 (weeks-months) Biowin4 (Primary Survey Model) : 3.5254 (days-weeks )

12.5 MITI生物降解的可能性

Biowin5 (MITI Linear Model) : 0.1510 Biowin6 (MITI Non-Linear Model): 0.0874

12.6 厌氧生物降解的可能性

Biowin7 (Anaerobic Linear Model): 0.1640

12.7 现成的生物降解性预测

NO

12.8 碳氢化合物生物降解

Structure incompatible with current estimation method!/

12.9 对气溶胶的吸附

Vapor pressure (liquid/subcooled): 0.0327 Pa (0.000245 mm Hg) Log Koa (Koawin est ): 9.047 Kp (particle/gas partition coef. (m3/ug)): Mackay model : 9.18E-005 Octanol/air (Koa) model: 0.000274 Fraction sorbed to airborne particulates (phi): Junge-Pankow model : 0.00331 Mackay model : 0.00729 Octanol/air (Koa) model: 0.0214 /

12.10 羟基自由基反应

OVERALL OH Rate Constant = 103.3312 E-12 cm3/molecule-sec Half-Life = 0.104 Days (12-hr day; 1.5E6 OH/cm3) Half-Life = 1.242 Hrs

12.11 臭氧反应

No Ozone Reaction Estimation

12.12 空气中颗粒物吸附的分数(PHI

0.0053 (Junge,Mackay) Note: the sorbed fraction may be resistant to atmospheric oxidation/

12.13 土壤吸附系数

Koc : 3.999E+004 Log Koc: 4.602 /

12.14 /酸催化水解(25℃

Rate constants can NOT be estimated for this structure!/

12.15 利用对数KOW估算生物累积量

Log BCF from regression-based method = 1.904 (BCF = 80.17) log Kow used: 3.38 (estimated)/

12.16 废水处理中的去除

Total removal: 10.58 percent Total biodegradation: 0.16 percent Total sludge adsorption: 10.41 percent Total to Air: 0.00 percent (using 10000 hr Bio P,A,S)/

12.17 三级逸度模型

Mass Amount Half-Life Emissions (percent) (hr) (kg/hr) Air 0.0855 2.48 1000 Water 16.9 900 1000 Soil 82 1.8e+003 1000 Sediment 0.925 8.1e+003 0 Persistence Time: 1.16e+003 hr//

12.18 土壤中的迁移性

暂无数据

12.19 PBTVPVB的结果评价

暂无数据

12.20 其他环境有害作用

暂无数据

13部分:废弃处置

13.1 废物处理

方法产品

None

污染包装物

None

14部分:运输信息

14.1 联合国编号 / UN NUMBER

欧洲陆运危规 / ER/RID

None

国际海运危规 / IMDG

None

国际空运危规 / IATA-DGR

None

14.2 联合国运输名称 / UN PROPER SHIPPING NAME

欧洲陆运危规 

None

国际海运危规

None

国际空运危规 

None

14.3 运输危险类别 / TRANSPORT HAZARD CLASS(ES)

欧洲陆运危规 / ER/RID

None

国际海运危规 / IMDG

None

国际空运危规 / IATA-DGR

None

14.4 包裹组 / PACKAGING GROUP

欧洲陆运危规 / ER/RID

None

国际海运危规 / IM0DG

None

国际空运危规 / IATA-DGR

None

14.5 环境危害 / ENVIRONMENTAL HAZARDS

None

14.6 特殊防范措施 / SPECIAL PRECAUTIONS FOR USER

None

14.7 禁配物 / INCOMPATIBLE MATERIALS

None

15部分:法律法规信息

15.1 专门对此物质或混合物的安全,健康和环境的规章/法规

适用法规

《中华人民共和国安全生产法》、《职业病防治法》、《化学化工实验室安全管理规范》

其它的规定

《生产安全事故报告和调查处理条例》、《职业病防治法》、《职业安全和卫生法》美国1970

16部分:其他补充信息

其他信息

版权所有:BIOFOUNT BEIJING BIO TECH CO.,LTD 公司。许可无限制纸张拷贝,仅限于内部使用。

上述信息视为正确,但不包含所有的信息,仅作为指引使用。本文件中的信息是基于我们目前所知,就正确的安全提示来说适用于本品。该信息不代表对此产品性质的保证。BIOFOUNT公司及其附属公司对任何操作或者接触上述产品而引起的损害不负有任何责任。更多使用条款,参见发票或包装条的反面。

更多销售条款及条件请参见HTTP://WWW.BIO-FOUNT.COM/或发票或装箱单的背面。欲悉详情,请联系:SALES@BIO-FOUNT.COM

 

SDS 1.0 英文
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Chemical safety technical specification

Edition1.0

Prepared according to GB/T16483GB/T17519

Revision date10.07.2019

 

Date of printing19.02.2020

 

Date of initial preparation25.05.2017

WEBwww.bio-fount.com

SDS numberBIOFOUNT-HXH506470

Copyright: BIOFOUNT BEIJING BIO TECH CO.,LTD

Product numberBIOFOUNT-HXH506470

(1S)-1-Phenyl-1,2,3,4-tetrahydroisoquinoline

List of instructions

Part 1

chemicals and enterprise logo

Part 2

risk overview

Part 3

Composition / composition information

Part 4

first aid measures

Part 5

fire fighting measures

Part 6

Leakage Emergency Treatment

Part 7

handling and storage

Part 8

exposure control / personal protection

Part 9

physical and chemical properties

Part 10

stability and reactivity

Part 11

toxicological information

Part 12

ecological hazard information

Part 13

waste disposal

Part 14

Transport Information

Part 15

information on laws and regulations

Part 16

other supplementary information

Part 1: chemicals and enterprise logo

1.1 product identification

Product Name:

(1S)-1-Phenyl-1,2,3,4-tetrahydroisoquinoline

English Name

(1S)-1-Phenyl-1,2,3,4-tetrahydroisoquinoline

Product No.:

HXH506470

Brand:

BIOFOUNT

(CAS No.)

118864-75-8

1.2 details of suppliers of safety technical specifications

Name of manufacturer or supplier:

BIOFOUNT BEIJING BIO-TECH CO.,LTD

Manufacturing address:

59 Kangtai Avenue Binhai New District Tianjin

300450 TIANJIN CHINA

BIOFOUNT (Tianjin) Biotechnology Co., Ltd

Jiuzhou tonglvgu Health Industrial Park, No. 59, Kangtai Avenue, Binhai New Area, Tianjin

Post code: 300450

Phone number:

 

1.3 emergency consultation telephone

Emergency contact number:

 

1.4 recommended and restricted uses of the substance or mixture

Identified uses:

It is only used for scientific research and development, not for medicine, family or other purposes.

Part 2: risk overview

2.1 hazard categories of GHS

No data available

2.2 GHS labeling elements, including precautionary statements

Pictogram

No data available

Signal word

No data available

Declaration of danger

No data available

Warning statement

No data available

preventive measure

No data available

Accident response

1. In case of accident or emergency during the use of chemicals, the party concerned shall report to the person in charge of the emergency response team as soon as possible, and the emergency response team shall take measures to prevent the situation from expanding. 3. The emergency team shall take rescue measures for the victims.

Storage

No data available

Waste disposal

No data available

2.3 physical and chemical hazards

No data available

2.4 health hazards

No data available

2.5 environmental hazards

No data available

2.6 other hazards

No data available

Part 3: Composition / composition information

Substance / mixture

material 

3.1 substances

Molecular formula

C15H15N

molecular weight

209.29

CAS No.

118864-75-8

EC- number

No data available

According to the corresponding regulations, there is no need to disclose specific components.

Part 4: first aid measures

4.1 description of necessary first aid measures inhalation

inhalation

Inhalation: Immediately leave the contaminated area; take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing.

Skin contact

Skin:Immediately flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop, Immediately call a physician and be prepared to transport the victim to a hospital for treatment.

Eye contact

eyes: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. Immediately transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

Ingestion

Ingestion: Do not induce vomiting,If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and Immediately call a hospital or poison control center. Be prepared to transport the victim to a hospital if advised by a physician. If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body. DO NOT Induce vomiting.Immediately transport the victim to a hospital.

4.2 most important symptoms and health effects

The most important known symptoms and effects are described in the label (see Chapter 2.2) and / or Chapter 11

4.3 instructions and instructions for timely medical treatment and special treatment required

No data available

4.4 special tips for doctors

No data available

Part 5: fire fighting measures

5.1 extinguishing media

Fire extinguishing method and agent

Fires involving this compound should be controlled using a dry chemical, carbon dioxide, foam or Halon extinguisher.

5.2 special hazards from this substance or mixture

No data available

5.3 precautions and protection measures for fire fighting

In case of small-scale fire, masks shall be worn to prevent the inhalation of toxic gas. In case of fire, the emergency response system shall be started in time to evacuate to the upper air outlet, and the local fire department shall be contacted to put out the fire.

Part 6: Leakage Emergency Treatment

6.1 personnel protection measures, protective equipment and emergency disposal procedures

1. Start the emergency response system first after leakage. 2. Before leakage treatment, wear safety protection shoes, safety protection gloves (anti acid and alkali gloves are required for strong acid substances), and wear corresponding protective masks according to the inhalation risk.

For personal protection, see Part 8.

6.2 environmental protection measures

Refer to the treatment method of Fande biochemical waste to prevent harm to the environment. After treatment, the waste shall be treated by a qualified waste treatment structure to avoid environmental pollution. 

6.3 storage, removal methods and disposal materials of leaked chemicals

The leaked chemicals shall be treated according to the treatment method of Fande biological chemical waste. Before treatment, the leaking area shall be enclosed with chemical absorbent rock wool to form a "cofferdam" to prevent the leakage from expanding.

6.4 reference to other parts

See section 13 for disposal.

Part 7: handling and storage

7.1 precautions for safe operation

Please wear masks, gloves and other protective articles during use to avoid contact with skin, inhalation and accidental ingestion.

See Section 2.2 for precautions.

7.2 conditions for safe storage, including any incompatibility

It is unable to provide detailed data for the time being. Try to avoid mixed storage with other compounds and storage in dark and ventilated places.

Part 8: exposure control / personal protection

8.1 control parameters

Hazard composition and occupational exposure limit

No data available

8.2 exposure control

Appropriate technical controls

No data available

Personal protective equipment

Eye protection

Please use equipment tested and approved by official standards such as NIOSH (USA) or en 166 (EU) for eye protection.

Skin protection

Take out by hand: gloves must be inspected before use. Please use proper methods to remove the gloves (do not touch the outer surface of the gloves), and avoid any skin parts contacting the product. After use, please handle the contaminated gloves carefully according to relevant laws and regulations and effective laboratory rules and procedures. Please wash and dry your hands.

The selected protective gloves must meet the specifications given in regulation (EU) 2016 / 425 and the en 374 standard derived from it.

Full contact

Material: NBR

Minimum layer thickness 0.11 mm

Solvent penetration time: 480 minutes

Splash protection

Material: NBR

Minimum layer thickness 0.11 mm

Solvent penetration time: 480 minutes

If applied in solvent form or mixed with other substances, or under conditions different from those specified in en 374, please contact the supplier of gloves approved by EC. This recommendation is only suggestive and must be evaluated and confirmed by an industrial hygiene expert familiar with the specific situation our customer plans to use. This should not be interpreted as providing approval for any particular usage method.

Body protection

Choose physical protection measures according to the type, concentration and quantity of hazardous substances and specific workplace. The type of protective equipment must be selected according to the concentration and quantity of hazardous substances in the specific workplace.

respiratory system protection

There is no need to protect breathing. To protect against dust damage, use N95 (US) or P1 (EN 143) dust masks. Respirators use respirators and parts that have been tested and passed government standards such as NIOSH (US) or cen (EU).

Control of environmental exposure

Do not let the product into the sewer.

Part 9: physical and chemical properties

9.1 information on basic physical and chemical properties

Appearance and character

shapeNo data available

 

colourNo data available

smell

No data available

Odor threshold

No data available

PH value

No data available

Melting point / freezing point

87.0 to 91.0 deg-C

Initial boiling point and boiling range

338.4±11.0 °C at 760 mmHg

flash point

166.9±14.7 °C

Evaporation rate

No data available

Flammability (solid, gas)

No data available

High / low flammability or explosive limits

No data available

Vapor pressure

0.0±0.7 mmHg at 25°C

Vapor density

No data available

Density / relative density

1.1±0.1 g/cm3

Water solubility

No data available

Partition coefficient of n-octanol / water

Log POW:2.70

Air distribution coefficient of n-octanol

Log Kow used: 3.38 (KowWin est) Log Kaw used: -5.667 (HenryWin est) Log Koa (KOAWIN v1.10 estimate): 9.047 Log Koa (experimental database): None/

Spontaneous combustion temperature

No data available

decomposition temperature

No data available

viscosity

No data available

Explosion characteristics

No data available 

Oxidizing

No data available

Estimation of hydrosol from fragments

WatSol(v1.01est)=74.619mg/L 

Henry's law constant (25 ℃)

Bond Method : 5.27E-008 atm-m3/mole Group Method: Incomplete Henrys LC [VP/WSol estimate using EPI values]: 2.122E-008 atm-m3/mole/ 

9.2 other safety information

No data available

Part 10: stability and reactivity

10.1 stability

No data available

10.2 hazardous reactions

No data available

10.3 conditions to avoid

No data available 

10.4 prohibited substances

Strong oxidant 

10.5 hazardous decomposition products

No data available 

Part 11: toxicological information

11.1 toxicological impact information

toxicity

No data available

Skin corrosion / irritation

No data available 

Serious eye injury / eye irritation

No data available

Respiratory or skin allergies

No data available

Germ cell mutagenicity

No data available 

carcinogenicity

No data available 

Reproductive toxicity

No data available 

Specific target organ systemic toxicity (one exposure)

No data available 

Specific target organ systemic toxicity (repeated exposure)

No data available 

Inhalation hazard

No data available 

Additional description

No data available 

Part 12: ecological hazard information

12.1 ecotoxicity

No data available 

12.2 durability and degradability

No data available 

12.3 possibility of rapid biodegradation

Biowin1 (Linear Model) : 0.9845 Biowin2 (Non-Linear Model) : 0.9713 

12.4 expert investigation of biodegradation results

Biowin3 (Ultimate Survey Model): 2.7083 (weeks-months) Biowin4 (Primary Survey Model) : 3.5254 (days-weeks ) 

12.5 possibility of MITI biodegradation

Biowin5 (MITI Linear Model) : 0.1510 Biowin6 (MITI Non-Linear Model): 0.0874 

12.6 possibility of anaerobic biodegradation

Biowin7 (Anaerobic Linear Model): 0.1640 

12.7 ready made biodegradability prediction

NO 

12.8 hydrocarbon biodegradation

Structure incompatible with current estimation method!/ 

12.9 adsorption of aerosols

Vapor pressure (liquid/subcooled): 0.0327 Pa (0.000245 mm Hg) Log Koa (Koawin est ): 9.047 Kp (particle/gas partition coef. (m3/ug)): Mackay model : 9.18E-005 Octanol/air (Koa) model: 0.000274 Fraction sorbed to airborne particulates (phi): Junge-Pankow model : 0.00331 Mackay model : 0.00729 Octanol/air (Koa) model: 0.0214 / 

12.10 hydroxyl radical reaction

OVERALL OH Rate Constant = 103.3312 E-12 cm3/molecule-sec Half-Life = 0.104 Days (12-hr day; 1.5E6 OH/cm3) Half-Life = 1.242 Hrs 

12.11 ozone reaction

No Ozone Reaction Estimation 

12.12 fraction of particulate adsorption in air (PHI)

0.0053 (Junge,Mackay) Note: the sorbed fraction may be resistant to atmospheric oxidation/ 

12.13 soil adsorption coefficient

Koc : 3.999E+004 Log Koc: 4.602 / 

12.14 alkali / acid catalyzed hydrolysis (25 ℃)

Rate constants can NOT be estimated for this structure!/ 

12.15 estimating bioaccumulation using log Kow

Log BCF from regression-based method = 1.904 (BCF = 80.17) log Kow used: 3.38 (estimated)/ 

12.16 removal in wastewater treatment

Total removal: 10.58 percent Total biodegradation: 0.16 percent Total sludge adsorption: 10.41 percent Total to Air: 0.00 percent (using 10000 hr Bio P,A,S)/ 

12.17 three level fugacity model

Mass Amount Half-Life Emissions (percent) (hr) (kg/hr) Air 0.0855 2.48 1000 Water 16.9 900 1000 Soil 82 1.8e+003 1000 Sediment 0.925 8.1e+003 0 Persistence Time: 1.16e+003 hr// 

12.18 mobility in soil

No data available 

12.19 evaluation of PBT and vpvb results

No data available 

12.20 other harmful effects on the environment

No data available 

Part 13: waste disposal

13.1 waste treatment

Product method

None 

Contaminated packaging

None 

Part 14: Transport Information

14.1 UN number

ADR/RID

None 

IMDG

None 

IATA-DGR

None 

14.2 UN proper shipping name

ADR/RID

None 

IMDG

None 

IATA-DGR

None 

14.3 Transport hazard class(es)

ADR/RID

None 

IMDG

None 

IATA-DGR

None 

14.4 Packaging group

ADR/RID

None 

IM0DG

None 

IATA-DGR

None 

14.5 Environmental hazards

None 

14.6 Special precautions for user

None 

14.7 Incompatible materials

None 

Part 15: information on laws and regulations

15.1 rules / regulations specific to the safety, health and environment of the substance or mixture

Applicable laws and regulations

None 

Other provisions

None 

Part 16: other supplementary information

Other information

Copyright:FOUNT BEIJING BIO TECH CO.,LTD. Unlimited paper copies are permitted, for internal use only.

The above information is deemed to be correct, but does not contain all information. It is only used as a guide. The information in this document is based on what we know at present and is applicable to this product in terms of correct safety tips. This information does not guarantee the nature of this product. Biofount and its affiliates shall not be liable for any damage caused by any operation or contact with the above products. For further terms of use, see the reverse side of the invoice or packing slip. For further terms and conditions of sale, please refer to http://www.bio-foundation.com/ or the back of the invoice or packing list.

The logo on the header or footer of this document may temporarily not visually match the product purchased as we are transitioning our brand. However, all information about the products in this article remains unchanged and is consistent with the products ordered. For more information, please contact: sales@bio-foundation.com

 

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